Trotz zahlreirher Versuche, den als Ligand in Uberganpsmctallkomplexen gebundenen Stickstoff zii reduzieren I 1.1, [2] nurden bisher Erfolge niir mit metallorganischen Kediiktionssystemen nach VoE'pin-Shur [3] erzielt. D a z n gehijren erfolgreiche Versuche, instabile Ki,-Metallkomplexe als Zwischen
P4-31
✍ Scribed by Nilsson, Brian; Dixen, Ulrik; Chen, Xu; Pehrson, Steen; Køber, Lars; Hilden, Jørgen; Svendsen, Jesper H.
- Book ID
- 121916528
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 61 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1547-5271
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📜 SIMILAR VOLUMES
The 3iP NMR spectrum of P&, in CS1 solution belongs to the AzX2 system (6 = 83.3 and 110.7 ppm respectively, downfield from D3P0,); this confirms the C\_ q,, symmetry of the free molecule. No P-S-P coupling is observed; this anomaly is discussed by comparison with related compounds.
The rotational dynamics of P O S and P O in the solid state were studied by means of 31 P NMR spectra of spinning and 4 6 4 7 static powder samples in the temperature range of 153-295 K and 295-388 K, respectively. All spectra were simulated to confirm the type of the motion and to extract the time