p-Benzylation of Duryl o-Methoxyphenyl Ketone with the Grignard Reagent 1
β Scribed by FUSON, REYNOLD C.; McARTHUR, COLIN R.
- Book ID
- 127323998
- Publisher
- American Chemical Society
- Year
- 1962
- Tongue
- English
- Weight
- 380 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
The addition of Grignard reagents to the o-amino aryl carboxylic acids without any additive forms the tertiary carbinol as a major product. Unexpectedly, the aryl ketones are formed as the only isolated product if o-amino moiety of anthranilic acids is protected with Boc, trifluoroacetyl, and pivalo
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