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Oxymercuration of strained olefins. Effect of syn-7 substituents

✍ Scribed by Tidwell, T. T.; Traylor, T. G.

Book ID
126453379
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
889 KB
Volume
33
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

Effect of a remote substituent on regios
Effect of a remote substituent on regioselectivity in oxymercuration of unsymmetrically substituted norbornenes
✍ Peter Mayo; Marc Poirier; Jan Rainey; William Tam πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 229 KB

The effect of a remote substituent on the regioselectivity in the oxymercuration of unsymmetrical substituted norbornenes has been investigated. Moderate to high levels of regioselectivity were observed with both exo-and endo-substituents at C-2 of norbornenes.

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In 1939 Lucas, et al., 1 proposed that the oxymercuration of olefins occurred by a trans addition and that the trans addition proceeded via mercurinium ion intermediates. Recent numerous investigations2 of the oxymercuration of unstrained olefins support the proposed formation of an intermediate mer