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Studies on the oxymetalation of olefins oxymercuration of bicyclo[3.2.1]Octa-2,7-diene

✍ Scribed by Mitsuru Sakai

Book ID: 104246653
Publisher: Elsevier Science
Year: 1973
Tongue: French
Weight: 205 KB
Volume: 14
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)95658-8

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✦ Synopsis

In 1939 Lucas, et al., 1 proposed that the oxymercuration of olefins occurred by a trans addition and that the trans addition proceeded via mercurinium ion intermediates. Recent numerous investigations2 of the oxymercuration of unstrained olefins support the proposed formation of an intermediate mercurinium ion, although it was established that strained olefins such as norbornene derivatives undergo exclusive cis-exo oxymercuration3 (es. 1).

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