Synthesis Of Chiral Bicyclo[2.2.2]octa-5,7-dien-2-ones 1
โ Scribed by Srikrishna, A.; Danieldoss, S.; Sharma, G. V. R.
- Book ID
- 126559277
- Publisher
- Taylor and Francis Group
- Year
- 1997
- Tongue
- English
- Weight
- 305 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0039-7911
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๐ SIMILAR VOLUMES
Chiral Synthons from Carvone. Part 22. Synthesis of Chiral Bicyclo(2.2. 2)octa-5,7-dien-2-ones. -The title compounds (II) and (V) are prepared as part of a programme on the total synthesis of chiral cerapicanes. -(SRIKRISHNA, A.;
## Abstract The photochemistry of 1,3,3โtrimethylbicyclo[2.2.2]octaโ5,7โdienโ2โones **1a**โ**f** containing multiple chromophoric moieties under various conditions is described. Upon direct irradiation, dienones **1a**โ**f** in benzene, acetonitrile, and methanol were found to aromatize through pho