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Oxygen donor potential of carbonyl oxide and dioxirane: a DFT study

✍ Scribed by C. Selçuki; V. Aviyente

Book ID
114143700
Publisher
Elsevier Science
Year
1999
Tongue
English
Weight
513 KB
Volume
492
Category
Article
ISSN
0166-1280

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Thianthrene 5-oxide (SSO) constitutes a useful mechanistic tool for the assessment of the electronic character of oxygen transfer agents by means of their X,, values, which reflect the extent of nucleophilic oxidation at the SO site in SSO. Treatment of dioxiranes 1 a-d with the SSO probe confirms t