Reaction Modes of Carbonyl Oxide, Dioxirane, and Methylenebis(oxy) with Ethylene: A New Reaction Mechanism
โ Scribed by Crehuet, Ramon; Anglada, Josep M.; Cremer, Dieter; Bofill, Josep M.
- Book ID
- 115544410
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 201 KB
- Volume
- 106
- Category
- Article
- ISSN
- 1089-5639
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๐ SIMILAR VOLUMES
## Abstract The initiation of free radical chain reactions by singlet carbene biradicals is proposed for homogeneous oxidation of typical unsaturated hydrocarbons, including ethylene, allene, and propyne. The mechanism features the production of singlet vinylidene and methylvinylidene by 1,1โH~2~ e
## on the occasion of his 65th birthday In spite of the high interest in halide salts as promoters for a variety of carbon ยฑ carbon bond-forming reactions, [1ยฑ4] little is known about the reactivity of simple carbonyl(halo)ruthenium(ii) complexes such as the interconvertible species 1 ยฑ 3 (Scheme