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Reactions of a Transient Carbonyl(chloro)(hydrido)ruthenium(II) Complex with Ethylene, Alkynes, and CO; Chemistry of the New Anion [Ru2(CO)4Cl5]−

✍ Scribed by Matthieu Faure; Luc Maurette; Bruno Donnadieu; Guy Lavigne


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
146 KB
Volume
38
Category
Article
ISSN
0044-8249

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✦ Synopsis


on the occasion of his 65th birthday

In spite of the high interest in halide salts as promoters for a variety of carbon ± carbon bond-forming reactions, [1±4] little is known about the reactivity of simple carbonyl(halo)ruthenium(ii) complexes such as the interconvertible species 1 ± 3 (Scheme 1). [5] thf C C Cl Ru C O O O Cl C C Cl Ru C O O O Cl C