Si-Fluorinated, C-chlorinated carbosilanes such as ( 3 d ) , ( 4 c ] , and ( 5 d ) are readily accessible in good yields, however, by photochlorination of the CH, groups in compounds of type (3 b ) -( 5 b) (see Table ). 'H-NMR studies of the reaction course in CC1, solution show that partially chlor
Oxygen-Bridged Carboxylato Complexes of Cobalt, Rhodium, and Iridium.
β Scribed by A. N. Belyaev; S. A. Simanova
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 24 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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Treatment of [[M(mu-Cl)(diolefin)](2)] with the lithium salts of primary and secondary amines (LiNRR') in diethyl ether affords the complexes [[M(mu-NRR')(diolefin)](2)] (M=Rh, Ir; diolefin=1,5-cyclooctadiene (cod), tetrafluorobenzobarrelene (tfb); R'=H, R=tBu, Ph, 4-MeC(6)H(4); R=R'=Ph, 4-MeC(6)H(4
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The synthesis and characterization of heterobimetallic and complexes are formed in nearly quantitative yields by metathesis reactions from the respective homodimeric mixed-valence complexes in which orthometalated [(ppy) 2 MCl] (M = Rh, Ir; ppy = 2-phenylpyridine anion) and compounds. The structures