Dinuclear Pentamethylcyclopentadienyl Rhodium and Iridium Complexes from C=C-Bridged Amino Acid Dimers
β Scribed by Harald Dialer; Susanne Schumann; Kurt Polborn; Wolfgang Steglich; Wolfgang Beck
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 322 KB
- Volume
- 2001
- Category
- Article
- ISSN
- 1434-1948
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Two precursors of the chiral dithiolato ligands, di-[(2R)-acetylmercaptopropyl] phthalate and isophthalate, 1 and 2 respectively, were synthesized from (S)-lactic acid. Reactions of 1 and 2 with [Rh 2 (m)-OMe) 2 (cod) 2 ] (cod = 1,5-cyclo-octtadiene) yielded rhodium thiolato complexes of different n