Heterobimetallic and Mixed-Valence Chloro-Bridged Complexes with Orthometalated Rhodium(III) and Iridium(III) Fragments
✍ Scribed by Kurt Polborn; Kay Severin
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 324 KB
- Volume
- 1998
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
✦ Synopsis
The synthesis and characterization of heterobimetallic and complexes are formed in nearly quantitative yields by metathesis reactions from the respective homodimeric mixed-valence complexes in which orthometalated [(ppy) 2 MCl] (M = Rh, Ir; ppy = 2-phenylpyridine anion) and compounds. The structures of [(ppy) 2 Rh(µ-Cl) 2 Rh(cod)] (cod = η 4 -1,5-cyclooctadiene) and [(ppy) 2 Rh(µ-Cl) 2 Pt(PBu 3 )-[(bzq) 2 RhCl] (bzq = benzo[h]quinoline anion) fragments are linked via chloro-bridges with rhodium(I), iridium(I), Cl] were determined by X-ray structure analyses. palladium(II), and platinum(II) fragments is reported. These