Oxygen Activation on Nickel(II)tetrahydrosalen Complexes with the Formation of Nickel(II)dihydrosalen Complexes
✍ Scribed by Dipl.-Ing. Arnd Böttcher; Prof. Dr. Horst Elias; Dipl.-Ing. Lutz Müller; Dr. Helmut Paulus
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 365 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
The pressure-jump method has been used to determine the rate constants for the formation and dissociation of nickel(I1) and cobalt(I1) complexes with cinchomeronate in aqueous solution at zero ionic strength. The forward and reverse rate constants obtained are k, = 2.27 x lo6 M-' s-' and k, = 3.81 x
## Abstract The acidity of malondialdehyde as well as the stability of its 1 :1‐complexes with Ni^II^ and Cu^II^ have been determined (Table). In comparison with the enolates of aliphatic β‐dike‐tones the anion C~3~H~3~O~2~− has not only a strikingly reduced basicity, but is also a grossly inferior