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Unusual Reaction Pathways in the Photolysis of Diazido(phosphane)nickel(II) Complexes: Nitrenes As Intermediates in the Formation of Nickel(0) Complexes

✍ Scribed by Prof. Dr. Horst Henning; Dr. Katrin Hofbauer; Dipl.-Chem. Kartin Handke; Dr. Rainer Stich


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
380 KB
Volume
36
Category
Article
ISSN
0044-8249

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The primary photoreactions due to charge transfer excitation of d 8 transition metal complexes of [MP 2 (N 3 ) 2 ] constitution (P 2 : mono-or diphosphane ligands) are strongly influenced by the central ion. While [MP 2 (N 3 ) 2 ] complexes of both palladium(II) and platinum(II) yield primarily the