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Oxycyclopropanes in organochemical synthesis. Total syntheses of (-)-valeranone and (.+-.)-grandisol

✍ Scribed by Wenkert, Ernest; Berges, David A.; Golob, Norman F.


Book ID
121426313
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
702 KB
Volume
100
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES


Total syntheses of epothilones B and D:
✍ Nathaniel Martin; Eric J Thomas πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 83 KB

Following exploratory studies which culminated in syntheses of the alcohol 16, a total synthesis of epothilones B and D is reported in which the trisubstituted 12,13-double-bond is introduced stereoselectively using the tin(IV) bromide-promoted reaction between the allylstannane 22 and the aldehyde