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Oxo-Centered Mixed-Ligand Triruthenium Complexes Having Redox-Active N -Methyl-4,4‘-bipyridinium Ions (mbpy + ). Reversible Multistep Electrochemical Properties of [Ru III2 Ru II (μ 3 -O)(μ-CH 3 CO 2 ) 6 (mbpy + ) 2 (CO)] 2+ and [Ru III3 (μ 3 -O)(μ-CH 3 CO 2 ) 6 (mbpy + ) 2 (L)] 3+ (L = H 2 O and N -Heterocyclic Ligands)

✍ Scribed by Abe, Masaaki; Sasaki, Yoichi; Yamada, Yasuko; Tsukahara, Keiichi; Yano, Shigenobu; Yamaguchi, Tadashi; Tominaga, Masato; Taniguchi, Isao; Ito, Tasuku


Book ID
118749513
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
358 KB
Volume
35
Category
Article
ISSN
0020-1669

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✍ Minna Jakonen; Pipsa Hirva; Taina Nivajärvi; Mirja Kallinen; Matti Haukka 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 275 KB

## Abstract The reductive carbonylation of ruthenium and osmium halides in the presence of cobalt and iron surfaces was studied. In these surface‐assisted reactions the metal surface plays an active role in releasing metal ions, which can be used for the in situ synthesis of mixed‐metal compounds.