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Terminal water ligand exchange and substitution by isonicotinamide on the oxo-centred triruthenium(III) complex [Ru3(μ3-O)(μ-CH3CO2)6(OH2)3]+. Crystal structure of [Ru3(μ3-O)(μ-CH3CO2)6(OH2)3]ClO4·HClO4·H2O

✍ Scribed by Glenmore Powell; David T. Richens; Anne K. Powell


Book ID
108324921
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
896 KB
Volume
213
Category
Article
ISSN
0020-1693

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Electronic structure of two heterotrinuc
✍ M. Velayutham; C.S. Gopinath; S. Subramanian 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 397 KB

Two 1~3-oxo carboxylate-bridged heterotrinuclear (ruthenium, cobalt) [Ru2Co(~3-O)(I.I,-CH3CO2)6L 3] (L = H20, Py) complexes have been prepared. EPR studies at 77 K show that there is no interaction between the ruthenium and cobalt ions. The ground state of high-spin cobalt is a spin doublet and the