Electronic structure of two heterotrinuc
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M. Velayutham; C.S. Gopinath; S. Subramanian
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Article
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1996
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Elsevier Science
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English
⚖ 397 KB
Two 1~3-oxo carboxylate-bridged heterotrinuclear (ruthenium, cobalt) [Ru2Co(~3-O)(I.I,-CH3CO2)6L 3] (L = H20, Py) complexes have been prepared. EPR studies at 77 K show that there is no interaction between the ruthenium and cobalt ions. The ground state of high-spin cobalt is a spin doublet and the