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Oxo-alkyls of chromium(V) and chromium(VI)

✍ Scribed by Noh, Seok Kyun; Heintz, Robert A.; Haggerty, Brian S.; Rheingold, Arnold L.; Theopold, Klaus H.


Book ID
126051624
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
285 KB
Volume
114
Category
Article
ISSN
0002-7863

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A unique feature of corroles relative to porphyrins and other related ligands is their ability to stabilize transition-metal ions in high oxidation states. [1,2] This phenomenon can not be related to the traditional means of obtaining high-valent metal complexes, which relies on p-donating and nonox