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Chromium(V) and Chromium(VI) Nitrido Complexes of Tris(pentafluorophenyl)corrole

✍ Scribed by Galina Golubkov; Zeev Gross


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
132 KB
Volume
42
Category
Article
ISSN
0044-8249

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✦ Synopsis


High-Oxidation-State Cr Complexes Chromium(v) and Chromium(vi


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A unique feature of corroles relative to porphyrins and other related ligands is their ability to stabilize transition-metal ions in high oxidation states. [1,2] This phenomenon can not be related to the traditional means of obtaining high-valent metal complexes, which relies on p-donating and nonox

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Selective permeation of vanadium(V) and chromiwn(V1) using three types of membrane systems war studied. The first was an mion exchange membrane, the second and third were supported liquid membranes containing either a terhhry mine or a qualernury ammonium salt. The membrane was sandwiched between tw