Preparation of Chromium(V) Fluoride and Chromium(VI) Fluoride
β Scribed by Prof. Dr. O. Glemser; Dipl.-Chem. H. Roesky; cand. chem. K.-H. Hellberg
- Publisher
- John Wiley and Sons
- Year
- 1963
- Tongue
- English
- Weight
- 233 KB
- Volume
- 2
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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High-Oxidation-State Cr Complexes Chromium(v) and Chromium(vi
A unique feature of corroles relative to porphyrins and other related ligands is their ability to stabilize transition-metal ions in high oxidation states. [1,2] This phenomenon can not be related to the traditional means of obtaining high-valent metal complexes, which relies on p-donating and nonox
## Abstract WF~6~ reacts with phosphines R~3~P forming 1:1 compounds. With R=P(CH~3~)~3~ the coordination around the tungsten atom is capped trigonal prismatic, with R=P(CH~3~)~2~C~6~H~5~ the coordination is capped octahedral, as established by singleβcrystal structure determinations: [(CH~3~)~3~Pο£Ώ