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Oxidative electrodimerization of 1,3-dithioles to tetrathiafulvalenes

✍ Scribed by Saeva, Franklin D.; Morgan, Bradley P.; Fichtner, Michael W.; Haley, Neil F.

Book ID
126100915
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
233 KB
Volume
49
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

1.2-1β€².2β€²-Tetrathiafulvalene [3-(1.2-dit
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Donor-Acceptor-Komplexe des 1.3-II.3 '-Tetrathiafulvalene 1 und des Selen-Analogen mit Tetracyanochinodimethan zeigen im Festzustand ungewijhnlich hohe anisotrope elektronische Leitflihigkeit ("Organiache Hetalle") 1) , das sugehijrige Tetrathiafulvaleniumchlorid Ralbleiter-Eigenschaften 213) . Vert

Versatile reactivity of 2-lithio-1,3-dit
Versatile reactivity of 2-lithio-1,3-dithioles: Formation of symmetrical and unsymmetrical tetrathiafulvalenes
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Reacting 2-lithio-1,3-dithioles with 1,3-dithiolium salts results in formation of both symmetrical and unsymmetrical tetrathiafulvalenes. The symmetrical tetra-thiafulvalenes are probably formed via a carbene intermediate which is generated by loss of an hydride from the 2-lithio-1,3dithioles.

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