Oxidative demethylation of 4-substituted N,N-dimethylanilines with iodine and calcium oxide in the presence of methanol
β Scribed by Acosta, Kirk; Cessac, James W.; Rao, P. Narasimha; Kim, Hyun K.
- Book ID
- 120572752
- Publisher
- The Royal Society of Chemistry
- Year
- 1994
- Tongue
- English
- Weight
- 222 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0022-4936
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Lignin peroxidase catalyses the oxidative N-demethylation of ring-substituted N,N-dimethylanilines by an electrontransfer mechanism whereby an anilinium radical cation is formed which is then deprotonated by the enzyme. Information on the nature of the basic centre which deprotonates the radical cat