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Oxidative cyclisation of a tricarbonylcyclohexadieneiron complex using ferric chloride on silica gel

โœ Scribed by Chi Wi Ong; Anthony J. Pearson

Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
131 KB
Volume
21
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Treatment of the diene-Fe(C0)3 complex (2) with dehydrated ferric chloride on silica gel support results in oxidative cyclisation of the alcohol function onto the diene ligand to give (3). This contrasts with the normal behaviour of both diene-Fe(C0)3 complexes and alcohols toward ferric chloride.

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