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Oxidative Cleavage of p -Methoxybenzyl Ethers with Methyl(trifluoromethyl)dioxirane

โœ Scribed by Paquette, Leo A.; Kreilein, Matthew M.; Bedore, Matthew W.; Friedrich, Dirk


Book ID
126792774
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
81 KB
Volume
7
Category
Article
ISSN
1523-7060

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Chemo- and diastereoselectivities in the
โœ Lucia D'Accolti; Michele Fiorentino; Caterina Fusco; Angela M. Rosa; Ruggero Cur ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 322 KB

A comparison of the diastereoselectivity and the chemoselectivity (epoxidation versus allylic oxidation) attained in the oxidation of cyclopentenols using dimethyldioxirane and methyl(trifluoromethyl)dioxirane is reported. The results indicate that with both dioxiranes diastereoselective epoxidation