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Oxidations by methyl trifluoromethyl dioxirane. Epoxidation of enol ethers

โœ Scribed by Luigino Troisi; Luigi Cassidei; Luigi Lopez; Rossella Mello; Ruggero Curci

Book ID
104227009
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
275 KB
Volume
30
Category
Article
ISSN
0040-4039

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Oxidations by methyl(trifluoromethyl)dio
Oxidations by methyl(trifluoromethyl)dioxirane. 3. Selective polyoxyfunctionalization of adamantane
โœ Rossella Mello; Luigi Cassidei; Michele Fiorentino; Caterina Fusco; Ruggero Curc ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 305 KB

Adamantme (1) can be amvuted dimtly into adamantan-1.3.5trio1 (5) and into adamantan-1.3.5.7~tetraosool (6) mu&r remarkably mild conditions by employing an exw of isolated mUby~~yMioxirane (3a) ia sob&m\_ This new dioxime speck was fomd to be eve 7,ooO-fold macmctivetbandkuethyldbxime(3b)iapaformiqe