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Oxidations by methyl(trifluoromethyl)dioxirane. 5. Conversion of alcohols into carbonyl compounds

✍ Scribed by Mello, Rossella; Cassidei, Luigi; Fiorentino, Michele; Fusco, Caterina; Huemmer, Walter; Jaeger, Volker; Curci, Ruggero


Book ID
119998648
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
572 KB
Volume
113
Category
Article
ISSN
0002-7863

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The solvent-dependent shift in the regioselectivity of the ge-allylic alcohols, additional steric interactions control the Ο€facial selectivity in the conformationally fixed transition raniol epoxidation by methyl(trifluoromethyl)dioxirane (TFD) reveals that as for the less reactive dimethyldioxirane