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ChemInform Abstract: Chemo- and Diastereoselectivities in the Oxidation of Cyclopentenols with Dimethyldioxirane and Methyl(trifluoromethyl)dioxirane.

✍ Scribed by Lucia D'Accolti; Michele Fiorentino; Caterina Fusco; Angela M. Rosa; Ruggero Curci


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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Regio-, Diastereo-, and Chemoselectiviti
✍ Waldemar Adam; Rodrigo Paredes; Alexander K. Smerz; L. Angela Valoza πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 353 KB πŸ‘ 2 views

The solvent-dependent shift in the regioselectivity of the ge-allylic alcohols, additional steric interactions control the Ο€facial selectivity in the conformationally fixed transition raniol epoxidation by methyl(trifluoromethyl)dioxirane (TFD) reveals that as for the less reactive dimethyldioxirane