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Oxidative carbonylation of aliphatic amines catalysed by nickel-complexes

✍ Scribed by Potenzo Giannoccaro; Cosimo Francesco Nobile; Pietro Mastrorilli; Nicoletta Ravasio


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
503 KB
Volume
419
Category
Article
ISSN
0022-328X

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ChemInform Abstract: Oxidation of Alipha
✍ L. ABIA; X. L. ARMESTO; M. CANLE L.; M. V. GARCIA; J. A. SANTABALLA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 1 views

Oxidation of Aliphatic Amines by Aqueous Chlorine. -A mechanistic study is done. The elementary step is the transfer of chlorine from the hypochlorous acid molecule to the nitrogen of the amino group. For primary and secondary amines H 2 O molecules are involved in the transition states.