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Oxidative Aromatic Coupling of meso -Arylamino-porphyrins

✍ Scribed by Nowak-Król, Agnieszka; Gryko, Daniel T.

Book ID
121366541
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
828 KB
Volume
15
Category
Article
ISSN
1523-7060

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Unusual phlorins from the oxidative coup
Unusual phlorins from the oxidative coupling of pentapyrromethanes: their facile conversion to meso-substituted porphyrins
✍ Jae-Won Ka; Chang-Hee Lee 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 74 KB

Direct, oxidant-mediated intramolecular coupling of pentapyrromethanes afforded 5-aryl-5-(2%-pyrryl)-10,15,20-triarylporphyrin (phlorins) as single products. The outcome of the reaction is comparable with the oxidative coupling of tetrapyrromethanes. Treatment of obtained phlorins with trifluoroacet