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Oxidation of meso-tetraphenylchlorins by dimethyl sulfoxide to the corresponding meso-porphyrins

โœ Scribed by Datta-Gupta, Nirmalendu; Williams, George E.


Book ID
111649790
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
407 KB
Volume
36
Category
Article
ISSN
0022-3263

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Unusual phlorins from the oxidative coup
โœ Jae-Won Ka; Chang-Hee Lee ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 74 KB

Direct, oxidant-mediated intramolecular coupling of pentapyrromethanes afforded 5-aryl-5-(2%-pyrryl)-10,15,20-triarylporphyrin (phlorins) as single products. The outcome of the reaction is comparable with the oxidative coupling of tetrapyrromethanes. Treatment of obtained phlorins with trifluoroacet