Oxidative addition of trifluoromethanesulfonamide to cycloocta-1,3-diene. Ring contraction rearrangement
β Scribed by Moskalik, M. Yu.; Astakhova, V. V.; Ushakov, I. A.; Shainyan, B. A.
- Book ID
- 125395713
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2014
- Tongue
- English
- Weight
- 163 KB
- Volume
- 50
- Category
- Article
- ISSN
- 1070-4280
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π SIMILAR VOLUMES
Diazoketones containing a 1,3-diene moiety were decomposed to yield corresponding vinylcyclopropanes stereospecifically. Transformation of vinylcyclopropanes to cyclopentenes is described and the scope of the reaction is discussed. The intramolecular addition of carbenoids to conjugated dienes has n
## Abstract Reactions of cyclohexanoneβderived enamines (I) with nitrobutene (II) affords cyclic nitronates (III) instead of the expected isomeric nitrones of type (V).
We have found that 1,3-dipolar additions to 3,3-dimethylcyclopropene sometimes give rearranged products, but the rearrangement products all derive from a normal 1,3-dipolar adduct. Wo products from 3,3-dimethylcyclopropene or methylenecyclopropane' additions have been found that would correspond to