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Stereospecific double rearrangement of trans-3,4-dimethyl-cis,trans-cycloocta-1,5-diene to cis-3,4-dimethyl-cis,cis-cycloocta-1,5-diene

✍ Scribed by Berson, Jerome A.; Dervan, Peter B.; Jenkins, Jerry A.

Book ID
125942778
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
229 KB
Volume
94
Category
Article
ISSN
0002-7863

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πŸ“œ SIMILAR VOLUMES

Thermal dimerization of 1,3-butadiene: K
Thermal dimerization of 1,3-butadiene: Kinetics of the formation of cis, cis-cycloocta-1,5-diene
✍ G. Huybrechts; L. Luyckx; Th. Vandenboom; B. Van Mele πŸ“‚ Article πŸ“… 1977 πŸ› John Wiley and Sons 🌐 English βš– 478 KB

## Abstract The thermal reaction of 1,3‐butadiene (BD) has been studied between 464 and 557Β°K at pressures between 49 and 450 torr. The products are 4‐vinylcyclohexene (VCH) and __cis__, __cis__‐cycloocta‐1,5‐diene (COD), and their formations are second order. The rate constant (in 1/mol Β· sec) for