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Oxidation state properties of delocalized, ligand-bridged metal complexes. [Ru3O(CH3CO2)6L3]n+ and the pyrazine-bridged, cluster-cluster dimer, [Ru3O(CH3CO2)6(py)2]2pyzm+

โœ Scribed by Wilson, Stephen T.; Bondurant, Richard F.; Meyer, Thomas J.; Salmon, Dennis J.


Book ID
127158336
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
388 KB
Volume
97
Category
Article
ISSN
0002-7863

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Electronic structure of two heterotrinuc
โœ M. Velayutham; C.S. Gopinath; S. Subramanian ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 397 KB

Two 1~3-oxo carboxylate-bridged heterotrinuclear (ruthenium, cobalt) [Ru2Co(~3-O)(I.I,-CH3CO2)6L 3] (L = H20, Py) complexes have been prepared. EPR studies at 77 K show that there is no interaction between the ruthenium and cobalt ions. The ground state of high-spin cobalt is a spin doublet and the