Oxidation ofd-glucose byN-bromophthalimide in the presence of chlorocomplex of iridium(III): a kinetic and mechanistic study
β Scribed by Ajaya Kumar Singh; Neerja Sachdev; Alpa Shrivastava; Bhawana Jain; Yokraj Katre
- Publisher
- Springer Netherlands
- Year
- 2011
- Tongue
- English
- Weight
- 401 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0922-6168
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The oxidation of __trans__βstilbene, phenylacetylene, and diphenylacetylene by Tl(OAc)~3~ in aqueous acetic acid medium in the presence of HClO~4~ follows the rate law in [H^+^] of 0.1β1.0__M__, the [H^+^] dependence below 0.1__M__ being marginal. The reactions are strongly dielectric
The stoichiometry and kinetics of the oxidation of ethylenediaminetetraacetate by [Fe(phen)3] 3 +, [Fe(bipy)3] 3 + and [ComW12040] 5-were studied in aqueous HC10 a. Reaction rates were first order with respect to the oxidants and the reductant, and the dependence of the second order rate constant k2