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Kinetic study of the ruthenium(III)-catalyzed oxidation of glycine byN-bromophthalimide in acidic medium

✍ Scribed by Ajaya Kumar Singh; Bhawana Jain; Reena Negi; Yokraj Katre; Surya P. Singh; Virender K. Sharma

Publisher: Springer
Year: 2010
Tongue: English
Weight: 423 KB
Volume: 35
Category: Article
ISSN: 0340-4285
DOI: 10.1007/s11243-010-9342-5

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## Abstract Kinetics of uncatalyzed and Ru(III)‐catalyzed oxidations of mono‐, di‐, and tri‐chloroacetic acids by the title compound (bromamine‐B or BAB) in HCl medium has been studied at 40°C. The uncatalyzed reaction shows a first‐order dependence of the rate on [BAB], and fractional and zero ord