Oxidation of tertiary polycycl1c amines by RuO4
β Scribed by Giancarlo Bettoni; Giuseppe Carbonara; Carlo Franchini; Vincenzo Tortorella
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- French
- Weight
- 541 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
Cyclohexanone monooxygenase catalyzes the asymmetric oxidation of some tertiary amines to amine N-oxides. The structure of the amine markedly influences the enantiomeric excess of products.
A chemical study of the oxidation of tertiary amines and alkaloids through monoelectronic transfer is presented and allows us to assign to singlet oxygen a new behavior as electron acceptor during the oxidation process.
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