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First asymmetric oxidation of tertiary amines by cyclohexanone monooxygenase

✍ Scribed by Gianluca Ottolina; Silvia Bianchi; Barbara Belloni; Giacoma Carrea; Bruno Danieli

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 281 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01780-3

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✦ Synopsis

Cyclohexanone monooxygenase catalyzes the asymmetric oxidation of some tertiary amines to amine N-oxides. The structure of the amine markedly influences the enantiomeric excess of products.

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