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Oxidation of Amines Catalyzed by Cyclohexanone Monooxygenase.

โœ Scribed by Stefano Colonna; Vincenza Pironti; Piero Pasta; Francesca Zambianchi


Publisher
John Wiley and Sons
Year
2003
Weight
148 KB
Volume
34
Category
Article
ISSN
0931-7597

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Enantioselective synthesis of tert-butyl
โœ Stefano Colonna; Nicoletta Gaggero; Giacomo Carrea; Piero Pasta; Veronique Alpha ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 78 KB ๐Ÿ‘ 1 views

Cyclohexanone monooxygenase from Acinetobacter calcoaceticus catalyzes the asymmetric oxidation of tert-butyl disulfide to enantiomerically pure (R)-tert-butyl tert-butanethiosulfinate. Lower enantioselectivities and conversions were observed in the oxidation of i-propyl, n-butyl, p-tolyl tert-butyl