On the gif oxidation of alicyclic tertiary amines
โ Scribed by D.H.R. Barton; J. Boivin; D. Gaudin; K. Jankowski
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- French
- Weight
- 141 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The recent paper by Deno and co-workers' has p-ted us to report the results obtaimd some time ago in our laboratory regarding the rearr vt of tertiary alicyclic hydroperoxides. Rearrangements of aliphatic alkyl hydroperoxides have not been explored in luch depth. Perhaps the most well-known example
Cyclohexanone monooxygenase catalyzes the asymmetric oxidation of some tertiary amines to amine N-oxides. The structure of the amine markedly influences the enantiomeric excess of products.
Fragmentary reports exist concerning transition metal-catalyzed air oxidations(l,2) or dehydrogenations of primary smines(J,4) or secondary amines(5). None of these results suggest that the catalytic systems are effective for oxidations of tertiary amines. In fact, Ralandin and Vasyunina(5) were ab