Oxidation of some catecholamines by sodium N-chloro-p-toluenesulfonamide in acid medium: A kinetic and mechanistic approach
β Scribed by Puttaswamy, ;Jagadeesh, R. ;Vaz, Nirmala
- Book ID
- 111487703
- Publisher
- Walter de Gruyter GmbH
- Year
- 2005
- Tongue
- English
- Weight
- 311 KB
- Volume
- 3
- Category
- Article
- ISSN
- 2391-5420
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## Abstract Kinetics of oxidation of Ξ± βamino acids, glycine, valine, alanine, and phenylalanine, by sodium Nβchloroβ__p__βtoluenesulfonamide or chloramineβT (CAT) has been investigated in HClO~4~ medium at 30Β°C. The rate shows firstβorder dependence on both CAT and amino acid concentrations and an
The kinetics of oxidation of benzhydrol and its p-substituted derivatives (YBH, where Cl, Br, NO 2 , CH 3 , and OCH 3 ) by sodium N-chloro-p-toluenesulfonamide or chlor-Y Ο H, amine-T (CAT), catalyzed by ruthenium(III) chloride, in the presence of hydrochloric acid in 30% (v/v) MeOH medium has been