𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Mechanistic Studies of Oxidation of Thiols to Disulfides by Sodium N -Chloro- p -toluenesulfonamide in an Alkaline Medium: A Kinetic Approach

✍ Scribed by Puttaswamy, ; Jagadeesh, R. V.


Book ID
118178516
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
104 KB
Volume
45
Category
Article
ISSN
0888-5885

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Kinetic and mechanistic studies of oxida
✍ D. S. Mahadevappa; K. S. Rangappa; N. M. M. Gowda; B. Thimme Gowda πŸ“‚ Article πŸ“… 1982 πŸ› John Wiley and Sons 🌐 English βš– 662 KB

The kinetics of oxidation of arginine, histidine, and threonine by chloramine-T (CAT) have been investigated in alkaline medium a t 35Β°C. The rates are first order in both [CAT] and [amino acid] and inverse fractional order in [OH-] for arginine and histidine. The rate is independent of [OH-] for th

Ruthenium(III)-catalyzed mechanistic stu
✍ H. Ramachandra; D. S. Mahadevappa; K. S. Rangappa; N. M. Made Gowda πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 190 KB πŸ‘ 2 views

The kinetics of oxidation of benzhydrol and its p-substituted derivatives (YBH, where Cl, Br, NO 2 , CH 3 , and OCH 3 ) by sodium N-chloro-p-toluenesulfonamide or chlor-Y Ο­ H, amine-T (CAT), catalyzed by ruthenium(III) chloride, in the presence of hydrochloric acid in 30% (v/v) MeOH medium has been

Oxidation of metronidazole with sodium N
✍ Puttaswamy; R. V. Jagadeesh; N. M. Made Gowda πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 English βš– 138 KB πŸ‘ 1 views

## Abstract A kinetic study of oxidation of metronidazole (Met) with sodium __N__‐bromo‐__p__‐toluenesulfonamide or bromamine‐T (BAT) has been carried out in HClO~4~ (30Β°C) and NaOH (40Β°C) media. The experimental rate laws obtained are –d[BAT]/d__t__=__k__[BAT][Met]^__x__^ [H^+^]^__y__^ in acid med