Mechanistic Studies of Oxidation of Thiols to Disulfides by Sodium N -Chloro- p -toluenesulfonamide in an Alkaline Medium: A Kinetic Approach
β Scribed by Puttaswamy, ; Jagadeesh, R. V.
- Book ID
- 118178516
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 104 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0888-5885
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The kinetics of oxidation of arginine, histidine, and threonine by chloramine-T (CAT) have been investigated in alkaline medium a t 35Β°C. The rates are first order in both [CAT] and [amino acid] and inverse fractional order in [OH-] for arginine and histidine. The rate is independent of [OH-] for th
The kinetics of oxidation of benzhydrol and its p-substituted derivatives (YBH, where Cl, Br, NO 2 , CH 3 , and OCH 3 ) by sodium N-chloro-p-toluenesulfonamide or chlor-Y Ο H, amine-T (CAT), catalyzed by ruthenium(III) chloride, in the presence of hydrochloric acid in 30% (v/v) MeOH medium has been
## Abstract A kinetic study of oxidation of metronidazole (Met) with sodium __N__βbromoβ__p__βtoluenesulfonamide or bromamineβT (BAT) has been carried out in HClO~4~ (30Β°C) and NaOH (40Β°C) media. The experimental rate laws obtained are βd[BAT]/d__t__=__k__[BAT][Met]^__x__^ [H^+^]^__y__^ in acid med