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Oxidation of organic compounds with cerium(IV). XVII. Oxidation of 1,2-diarylethanes

โœ Scribed by Trahanovsky, Walter S.; Brixius, Darryl W.


Book ID
127113465
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
420 KB
Volume
95
Category
Article
ISSN
0002-7863

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Oxidation of organic compounds with ceri
โœ Walter S. Trahanovsky; Marian Gordon Young; Paul M. Nave ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 183 KB

Although benzyl alcohols (2,3) and cyclopropanemethanol (4) are converted to the corresponding aldehydes in nearly quantitative yield by the oxidation with ceric ammonium nitrate (CAN), we have found that many other alcohols undergo a cleavage reaction when oxidized with CAN (1,5). In this communica