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Controlled Oxidation of Organic Compounds with Cerium(IV). II. The Oxidation of Toluenes

โœ Scribed by Trahanovsky, Walter S.; Young, L. Brewster

Book ID
120084386
Publisher
American Chemical Society
Year
1966
Tongue
English
Weight
474 KB
Volume
31
Category
Article
ISSN
0022-3263

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Oxidation of organic compounds with ceri
Oxidation of organic compounds with cerium(IV). IX. Formation of 2-methyltetrahydrofuran by oxidation of 1-pentanol
โœ Walter S. Trahanovsky; Marian Gordon Young; Paul M. Nave ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 183 KB

Although benzyl alcohols (2,3) and cyclopropanemethanol (4) are converted to the corresponding aldehydes in nearly quantitative yield by the oxidation with ceric ammonium nitrate (CAN), we have found that many other alcohols undergo a cleavage reaction when oxidized with CAN (1,5). In this communica