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Oxidation of organic compounds with cerium(IV). XI. Oxidative cleavage of 1,2-diarylethanols and 1-aryl-2,3-diphenylpropan-2-ols by cerium(IV) and chromic acid

โœ Scribed by Trahanovsky, Walter S.; Nave, Paul M.


Book ID
126438125
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
689 KB
Volume
93
Category
Article
ISSN
0002-7863

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Oxidation of organic compounds with ceri
โœ Walter S. Trahanovsky; Marian Gordon Young; Paul M. Nave ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 183 KB

Although benzyl alcohols (2,3) and cyclopropanemethanol (4) are converted to the corresponding aldehydes in nearly quantitative yield by the oxidation with ceric ammonium nitrate (CAN), we have found that many other alcohols undergo a cleavage reaction when oxidized with CAN (1,5). In this communica