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Oxidation of organic compounds with cerium(IV). XII. Oxidative cleavage and ketone formation of alkylphenylcarbinols

โœ Scribed by Trahanovsky, Walter S.; Cramer, Juergen


Book ID
121313854
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
620 KB
Volume
36
Category
Article
ISSN
0022-3263

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Oxidation of organic compounds with ceri
โœ Walter S. Trahanovsky; Marian Gordon Young; Paul M. Nave ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 183 KB

Although benzyl alcohols (2,3) and cyclopropanemethanol (4) are converted to the corresponding aldehydes in nearly quantitative yield by the oxidation with ceric ammonium nitrate (CAN), we have found that many other alcohols undergo a cleavage reaction when oxidized with CAN (1,5). In this communica