The kinetics of oxidation of arginine, histidine, and threonine by chloramine-T (CAT) have been investigated in alkaline medium a t 35ยฐC. The rates are first order in both [CAT] and [amino acid] and inverse fractional order in [OH-] for arginine and histidine. The rate is independent of [OH-] for th
Oxidation of indoles by n-chloro-n-sodio-p-toluenesulphonamide in alkaline medium catalysed by osmium(VIII): a kinetic study
โ Scribed by Kanchugarakoppal S. Rangappa; Daniel T. Esterline; Chirchingi K. Mythily; Dandinasivara S. Mahadevappa; Sarvottam Y. Ambekar
- Book ID
- 108428923
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 500 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0277-5387
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๐ SIMILAR VOLUMES
The kinetics of oxidation of the aliphatic primary amines, n-propylamine, n-butylamine, and isoamylamine, by N-sodio-N-bromobenznesulfonamide or bromamine-B (BAB), in the presence of osmium(VIII), has been studied in alkaline medium at 35ะC. In the presence of the catalyst, the experimental rate law
The kinetics of oxidation of Isoniazid (INH) by sodium N-haloarenesulfonamidates, chloramine-T (CAT), bromamine-T (BAT), chloramine-B (CAB), and bromamine-B (BAB), has been studied in alkaline medium at 303 K. The oxidation reaction follows identical kinetics with a first-order dependence on each [o