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Kinetics and mechanism of Ru(III)-catalysed oxidation of amino acids by N-chloro-N-sodio-toluene-p-sulphonamide in acid media

✍ Scribed by B Thimme Gowda; P Ramachandra

Book ID
112917072
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1990
Tongue
English
Weight
429 KB
Volume
102
Category
Article
ISSN
0253-4134

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## Abstract Kinetics of oxidation of Ξ± ‐amino acids, glycine, valine, alanine, and phenylalanine, by sodium N‐chloro‐__p__‐toluenesulfonamide or chloramine‐T (CAT) has been investigated in HClO~4~ medium at 30Β°C. The rate shows first‐order dependence on both CAT and amino acid concentrations and an