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Oxidation of hydrocarbons. IV. Kinetics and mechanism of the oxidative cleavage of cinnamic acid by acidic permanganate

✍ Scribed by Lee, Donald G.; Brownridge, James R.

Book ID
120618060
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
818 KB
Volume
96
Category
Article
ISSN
0002-7863

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Kinetics and mechanism of the oxidation of selenium(IV) by permanganate
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The oxidation of selenium(IV) by permanganate has been studied kinetically in acid, neutral and alkaline media. The reaction exhibits unit-order dependence on selenium(IV) and permanganate in all the three media. Manganese(VI) retards the reaction in alkaline medium. The rate-limiting step is the sa