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Mechanism of the permanganate oxidation of unsaturated compounds. Part IV. Kinetic investigation of the oxidation of maleic and fumaric acid

✍ Scribed by Sim�ndi, L�szl� I.; J�ky, Mikl�s

Book ID
127296443
Publisher
Royal Society of Chemistry
Year
1973
Tongue
English
Weight
587 KB
Volume
14
Category
Article
ISSN
1472-779X

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Kinetics and mechanism of the oxidation of selenium(IV) by permanganate
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The oxidation of selenium(IV) by permanganate has been studied kinetically in acid, neutral and alkaline media. The reaction exhibits unit-order dependence on selenium(IV) and permanganate in all the three media. Manganese(VI) retards the reaction in alkaline medium. The rate-limiting step is the sa