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Oxidation of furfural with H2O2 in the presence of a photogenerated iron catalyst

✍ Scribed by Françoise Moulines; Jaime Ruiz; Didier Astruc

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
137 KB
Volume
340
Category
Article
ISSN
0022-328X

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On the oxidation of saturated hydrocarbo
On the oxidation of saturated hydrocarbons with H2O2 in the presence of iron(II)-picolinate or iron(II)−1,10 phenanthroline 2-carboxylate.
✍ G. Balavoine; D.H.R. Barton; J. Boivin; A. Gref 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 261 KB

A new catalytic system for highly selective oxidation of saturated hydrocarbons into ketones is described. This system is based on the combination offerrous picolinate (or l,lOphenanthroline 2-carboqylate) and H202 in pyridine sohuion.Under these conditions cyclohexane gave mabdy cyclohmanone (90% ,