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Oxidation of hydrocarbons by O2 in the presence of VO(acac)2 as catalyst

✍ Scribed by László J. Csányi; Károly Jáky; Gábor Galbács

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
90 KB
Volume
179
Category
Article
ISSN
1381-1169

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Oxidation of adamantane with O2 catalyse
Oxidation of adamantane with O2 catalysed by VO(acac)2 and reactivity of active species in acetic acid
✍ Hirokazu Kobayashi; Ichiro Yamanaka 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 504 KB

The oxidation of adamantane (470 mM) catalysed by VO(acac) 2 (0.5 mM) with 1 atm O 2 in acetic acid at 393 K was studied. The major product was 1-adamantanol, and minor ones were 2-adamantanol and 2-adamantanone. The selectivity for 1-adamantanol (3 • -selectivity) was almost constant at 75% under a